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MIT OpenCourseWare

Thermodynamics & Kinetics

This subject deals primarily with equilibrium properties of macroscopic systems, basic thermodynamics, chemical equilibrium of reactions in gas and solution phase, and rates of chemical reactions. (from ocw.mit.edu )

Instructor

Prof. Keith A. Nelson and Prof. Moungi Bawendi.

Chemistry

2008

Lecture 01 - State of a System, 0th Law, Equation of State

Lecture 02 - Work, Heat, First Law

Lecture 03 - Internal Energy, Expansion Work

Lecture 04 - Enthalpy

Lecture 05 - Adiabatic Changes

Lecture 06 - Thermochemistry

Lecture 07 - Calorimetry

Lecture 08 - Second Law

Lecture 09 - Entropy and Clausius Inequality

Lecture 10 - Entropy and Irreversibility

Lecture 11 - Fundamental Equation, Absolute S, Third Law

Lecture 12 - Criteria for Spontaneous Change

Lecture 13 - Gibbs Free Energy

Lecture 14 - Multicomponent Systems, Chemical Potential

Lecture 15 - Chemical Equilibrium

Lecture 16 - Temperature, Pressure and Kp

Lecture 17 - Equilibrium: Application to Drug Design

Lecture 18 - Phase Equilibria - One Component

Lecture 19 - Clausius-Clapeyron Equation

Lecture 20 - Phase Equilibria - Two Components

Lecture 21 - Ideal Solutions

Lecture 22 - Non-ideal Solutions

Lecture 23 - Colligative Properties

Lecture 24 - Introduction to Statistical Mechanics

Lecture 25 - Partition Function (q) - Large N Limit

Lecture 26 - Partition Function (Q) - Many Particles

Lecture 27 - Statistical Mechanics and Discrete Energy Levels

Lecture 28 - Model Systems

Lecture 29 - Applications: Chemical and Phase Equilibria

Lecture 30 - Introduction to Reaction Kinetics

Lecture 31 - Complex Reactions and Mechanisms

Lecture 32 - Steady-state and Equilibrium Approximations

Lecture 33 - Chain Reactions

Lecture 34 - Temperature Dependence, Ea, Catalysis

Lecture 35 - Enzyme Catalysis

Lecture 36 - Autocatalysis and Oscillators